This page gives an overview of the results and publications of the GREENMAT group in the field of batteries.
GREENMAT
FolderDescription of our expertise in the synthesis and characterization of materials for energy storage applications
- Edith Roex (2024) : Design and Development of Advanced Electrode Materials for Li-ion and Zn-ion Batteries
- Jérôme Bodart (2022) : Development of Advanced Phosphate-based Cathode Materials for Na/K-ion Batteries by Spray-Drying Process
- Caroline Piffet (2021) : Spray-drying synthesis of Ti-based materials for Li/Na-ion batteries: development of Li4Ti5O12 flexible electrodes and in-situ characterizations of Na2Ti3O7
- Thomas Jungers (2020) : Sodium iron sulfate alluaudite solid solution for Na-ion batteries: Stoichiometry control through synthetic strategies
- Nicolas Eshraghi (2020) : Development of Na3V2(PO4)2F3/C and Si/C composites as high-performance electrode materials for Alkali-ion batteries using spray drying technique
- Claude Karegeya (2017) : Towards a development of iron phosphate-based materials as positive and negative electrodes for Li-ion batteries
- Magali Brisbois (2015) : Synthèse et caractérisation de Na2FePO4F comme matériau d’électrode positive pour les accumulateurs au lithium
- Claire Jamin (2014) : Synthèse et étude du composé Li4Ti5O12 comme électrode négative dans les accumulateurs Li-ion
- Sebastien Caes (2013) : Films minces mésoporeux d’oxydes de métaux de transition et de lithium : Influence du cation alcalin et de l’agent structurant sur la synthèse par soft templating
- Natacha Krins (2009) : Films minces mesoporeux d’oxydes mixtes de vanadium et de niobium comme électrode positive pour accumulateurs au lithium
- Hervé Limage (2008) : Substitution au manganèse dans LiNiO2 : synthèses, caractérisation structurale et étude électrochimique de l'insertion du lithium
- Published patent application : "Silicon-Carbon Composite Anode Material" (WO/2020/099589 A1 - 2020-05-22), N. Eshraghi, A. Mahmoud, R. Cloots, F. Boschini
- Published Patent Application : “Flexible thin-films for battery electrodes” (WO/2018/141659 A1), C. Piffet, F. Boschini, R. Cloots
Self-standing V2O5/Polydopamine/CNT film as high-performance cathode material for advanced zinc-ion batteries. E. Roex, A. Aqil, J. Światowska, C. Malherbe, F. Boschini, R. Cloots, A. Mahmoud. J. Power Sources 616 (2024) 235104
Unveiling the potential of Na2FePO4F@ PEG composite as cathode material for sodium-ion batteries. Z. El Kacemi, L. Fkhar, K. El Maalam, H. Aziam, H. Ben Youcef, I. Saadoune, M. Ait Ali, F. Boschini, A. Mahmoud, O. Mounkachi, M. Balli. J. Molecular Structure 1312 (2024) 138524
Direct NCA Cathode Active Materials Recycling from Spent Li-Ion Batteries: Solvent-Free Recovery and Healing by Heat Treatment. H. Oubaha, L. Fkhar, R. Cloots, F. Boschini, A. Mahmoud, ACS Sustainable Resour. Manage. 1 (2024) 1791-1801.
Downsizing and coating effects on the electrochemical performance of Mn-doped iron fluorophosphate as cathode material for sodium-ion batteries. Z. El Kacemi, L. Fkhar, K. El Maalam, H. Aziam, H. Ben Youcef, I. Saadoune, A. Mahmoud, F. Boschini, O. Mounkachi, M. Balli, J. Phys. Chem. Solids 190 (2024) 112008.
Electrical and dielectric study of Na2/3Mn2/3Fe1/3O2 as cathode active materials for sodium-ion batteries. F. Missaoui, M. Krimi, A. Mahmoud, F. Boschini, A. Ben Rhaiem, New J. Chem. 48 (2024) 12817-12827.
Effect of the Calcination Duration on the Electrochemical Properties of Na2Ti3O7 as Anode Material for Na-Ion Batteries. C. Piffet, N. Eshraghi, G. Mottet, F. Hatert, J. Światowska, R. Cloots, F. Boschini, A. Mahmoud, Batteries 9 (2023) 495.
From Na2FePO4F/CNT to NaKFePO4F/CNT as advanced cathode material for K-ion batteries. J. Bodart, N. Eshraghi, M.T. Sougrati, F. Boschini, P.E. Lippens, B. Vertruyen, A. Mahmoud, J. Power Sources 555 (2023) 232410.
Enhancement of the Na2FePO4F@gC3N4 electrochemical performance in view of its implementation in sodium-ion batteries. Z. El Kacemi, L. Fkhar, K. El Maalam, H. Aziam, H.B. Youcef, I. Saadoune, A. Mahmoud, F. Boschini, M.A.Ali, O. Mounkachi, M. Balli, Solid State Ionics 392 (2023) 116167.
Spray-dried V2O5 as cathode material for high-performance aqueous zinc-ion batteries. E. Roex, F. Boschini, V. Delaval, A. Schrijnemakers, R. Cloots, A. Mahmoud, J. Electroanal. Chem. 929 (2023) 117133.
High temperature X-ray diffraction study of the formation of Na2Ti3O7 from a mixture of sodium carbonate and titanium oxide. C. Piffet, B. Vertruyen, F. Hatert, R. Cloots, F. Boschini, A. Mahmoud, J. Energy Chem. 65 (2022) 210.
Deep Eutectic Solvents as Nonflammable Electrolytes for Durable Sodium-Ion Batteries. D. De Sloovere, D. E. P. Vanpoucke, A. Paulus, B. Joos, L. Calvi, T. Vranken, G. Reekmans, P. Adriaensens, N. Eshraghi, A. Mahmoud, F. Boschini, M. Safari, M. K. Van Bael, A. Hardy, Adv. Energy Sustainability Res. 3 (2022) 2100159.
Improving the electrochemical performances of organo-palladium (II) complex as promising anode material for Li-ion batteries: Effect of double emulsion preparation. E. Roex, K.S. Etsè, R. Cloots, F. Boschini, A. Mahmoud, Electrochimica Acta 391 (2021) 138935.
Electrochemical mechanism and effects of Fe doping and grinding process on the microstructural and electrochemical properties of Na2Co1-xFexSiO4 cathode material for sodium-ion batteries. K. Trabelsi, J. Bodart, F. Boschini, A.B. Rhaiem, A. Mahmoud, J. Power Sources 496 (2021) 229827.
Enhancing performances of Polydopamine as cathode for Lithium‐and Potassium‐ion batteries by simple grafting of sulfonate groups. Aqil, C. Jérôme, F. Boschini, A. Mahmoud, Batteries & Supercaps 4 (2021) 374.
Spray-dried K3V(PO4)2/C composites as novel cathode materials for K-ion batteries with superior electrochemical performance, J. Bodart, N. Eshraghi, T. Carabin, B. Vertruyen, R. Cloots, F. Boschini and A. Mahmoud, J. Power Sources 480 (2020) 229057.
Recovery of Nano-Structured Silicon from End-Of-Life Photovoltaic Wafers with Value-Added Applications in Lithium-Ion Battery, N. Eshraghi, L. Berardo, A. Schrijnemakers, V. Delaval, M. Shaibani, M. Majumder, R. Cloots, B. Vertruyen, F. Boschini, A. Mahmoud, ACS Sustainable Chemistry & Engineering 8 (2020) 5868.
Optimization of the compositions of polyanionic sodium-ion battery cathode NaFe2−xVx(PO4)(SO4)2, R. Essehli, A. Alkhateeb, A. Mahmoud, F. Boschini, H. Ben Yahia, R. Amin, I. Belharouak, J. Power Sources 469 (2020) 228417.
Influence of the Cyclic versus Linear Carbonate Segments in the Properties and Performance of CO2-Sourced Polymer Electrolytes for Lithium Batteries, F. Ouhib, L. Meabe, A. Mahmoud, B. Grignard, J.-M. Thomassin, F. Boschini, H. Zhu, M. Forsyth, D. Mecerreyes, C. Detrembleur, ACS Applied Polymer Materials 2 (2020) 922.
Aqueous processing of flexible, free-standing Li4Ti5O12 electrodes for Li-ion batteries, C. Piffet, B. Vertruyen, S. Caes, J.M. Thomassin, G. Broze, C. Malherbe, F. Boschini, R. Cloots, A. Mahmoud, Chem. Eng. J. 397 (2020) 125508.
Exploring organo-palladium(II) complexes as novel organometallic materials for Li-ion batteries, K. S. Etse, F. Boschini, C. Karegeya, E. Roex, G. Zaragoza, A, Demonceau, R. Cloots, A. Mahmoud, Electrochimica Acta 337 (2020) 135659
CO2-sourced polycarbonates as solid electrolytes for room temperature operating lithium batteries, F. Ouhib, L. Meabe, A. Mahmoud, N. Eshraghi, B. Grignard, J.-M. Thomassin, A. Aqil, F. Boschini, C. Jérôme, D. Mecerreyes, C. Detrembleur, J. Mater. Chem. A 16 (2019) 9844.
Sodium iron sulfate alluaudite solid solution for Na-ion batteries: moving towards stoichiometric Na2Fe2(SO4)3, T. Jungers, A. Mahmoud, C. Malherbe, F. Boschini, B. Vertruyen, J. Mater. Chem. A 7 (2019) 8226.
Electrochemical mechanism and effect of carbon nanotubes on the electrochemical performance of Fe1.19(PO4)(OH)0.57(H2O)0.43 cathode material for Li-ion batteries, A. Mahmoud, C. Karegeya, M.T. Sougrati, J. Bodart, B. Vertruyen, R. Cloots, P.E. Lippens, F. Boschini, ACS Applied Materials & Interfaces 10 (2018) 34202.
Facile solvothermal synthesis of Na1.5□0.5Mn1.5Fe1.5(PO4)3: Electrochemical study as a dual electrode material for lithium-ion batteries, C. Karegeya, A. Mahmoud, F. Hatert, R. Cloots, B. Vertruyen, P.E. Lippens, F. Boschini, Solid State Sciences 326 (2018) 18.
Li4Ti5O12 powders by spray-drying: influence of the solution concentration and particle size on the electrochemical properties, C. Jamin, T. Jungers, C. Piffet, A. Mahmoud, R. Cloots, B. Vertruyen, F. Boschini, J. Phys.: Conf. Ser. 1081 (2018) 012001.
Spray-drying of electrode materials for lithium- and sodium-ion batteries, B. Vertruyen, N. Eshraghi, C. Piffet, J. Bodart, A. Mahmoud, F. Boschini, Materials 11 (2018) 1076.
Na1.25Ni1.25Fe1.75(PO4)3 nanoparticles as a janus electrode material for Li-ion batteries, C. Karegeya, A. Mahmoud, F. Hatert, B. Vertruyen, R. Cloots, P.E. Lippens, F. Boschini, J. Power Sources 388 (2018) 57.
Continuous-porous N-doped carbon network as high-performance electrode for lithium-ion batteries, W. Alkarmo, F. Ouhib, A. Aqil, J.M Thomassin, B. Vertruyen, M.L. Piedboeuf, N. Job, C. Detrembleur, C. Jérôme, J. Mater. Sci. 53 (2018) 6135.
Spray drying as a tool to disperse conductive carbon inside Na2FePO4F particles by addition of carbon black or carbon nanotubes to the precursor solution, A. Mahmoud, S. Caes, M. Brisbois, R.P. Hermann, L. Berardo, A. Schrijnemakers, C. Malherbe, G. Eppe, R.Cloots, B. Vertruyen, F. Boschini, J. Solid State Electrochem. 22 (2018) 103.
Hydrothermal synthesis in presence of carbon black: particle-size reduction of iron hydroxyl phosphate hydrate for Li-ion battery, C. Karegeya, A. Mahmoud, R. Cloots, B. Vertruyen, F. Boschini, Electrochim. Acta 250 (2017) 49.
Hydrothermal self-assembly of sodium manganese iron phosphate particles: Growth mechanism and electrochemical performance in lithium-ion battery, C. Karegeya, A. Mahmoud, B.Vertruyen, F. Hatert, R. Cloots, F. Boschini, Solid State Ionics 312 (2017) 88.
One-step hydrothermal synthesis and electrochemical performance of sodium-manganese-iron phosphate as cathode material for Li-ion batteries, C. Karegeya, A. Mahmoud, B. Vertruyen, F. Hatert, R.P. Hermann, R. Cloots, F. Boschini, J. Solid State Chem. 253 (2017) 389.
Sodium vanadium (III) fluorophosphate / carbon nanotube composite (NVPF/CNT) prepared by spray-drying: good electrochemical performance thanks to well-dispersed CNT network within NVPF particles, N. Eshraghi, S. Caes, A. Mahmoud, R. Cloots, B. Vertruyen, F. Boschini, Electrochim. Acta 228 (2017) 319.
Na2FePO4F/multi-walled carbon nanotubes for lithium-ion batteries: operando Mössbauer study of spray-dried composites, M. Brisbois, S. Caes, B. Vertruyen, A. Schrijnemakers, R. Cloots, N. Eshraghi, R.P. Hermann, A. Mahmoud, M.T. Sougrati, F. Boschini, Sol. Energ. Mat. Sol. C. 148 (2016) 67.
Spray-drying synthesis of Na2FePO4F/Carbon powders for lithium-ion batteries, M. Brisbois, N. Krins, R.P. Hermann, A. Schrijnemakers, R. Cloots, B. Vertruyen, F. Boschini, Mater. Lett. 130 (2014) 263.
Effect of freeze-drying and self-ignition process on the microstructural and electrochemical properties of Li4Ti5O12, C. Jamin, K. Traina, D. Eskenazi, N. Krins, R. Cloots, B. Vertruyen, F. Boschini, Mater. Res. Bull. 48 (2013) 4641.
Structural and electrochemical characterization of mesoporous thin films of Nb2xV2−2xO5 upon lithium intercalation, N.Krins, L. Lepot, R. Cloots, B. Vertruyen, Solid State Ionics 180 (2009) 848.
LiMn2-xTixO4 spinel-type compounds (x ≤ 1) : structural, electrical and magnetic properties, N. Krins, F. Hatert, K. Traina, L. Dusoulier, I. Molenberg, J.F. Fagnard, Ph. Vanderbemden, A. Rulmont, R. Cloots, B. Vertruyen, Solid State Ionics 177 (2006) 1033.
